GST 2420: Atoms and Stars
An Historical Introduction to Astronomy, Physics, and Scientific
Discovery.
Fall 2002, Section 983, Call Number 16050
Agenda 11 for 11/13
- Announcements:
- Day scheduled as a Friday (noAtoms and Stars class) - November 27
- Course web site: http://www.cll.wayne.edu/isp/drbowen/aasf02
(also links from Pipeline). New today: supplementary information for GST
1990 (now vocabulary for Chapter 7 of God and Nature).
- Online Life at WSU updated and with live links at http://www.cll.wayne.edu/isp/drbowen/OnlineLife.
- Fliers for ISP 5660 / GIS 3340 (Creativity: Building the New) online. How do online courses work? For a general description, see Online Live
at WSU, above. To see this course the last
time it was taught (when it was AGS 3360) go to http://www.cll.wayne.edu/isp/drbowen/crtvyw02.
- For Essay 2, article by Bronowski starts on Reader Pg 254, article by
Nissani on Pg 261. Read these for next week.
- Personal remarks
- Agency
- Science as a social process
- Are there scientific revolutions? Some people say no - the changes are
too gradual
- Telescope experiment
- Science in the news
- What makes us decide that a line or edge is straight? Weight.
Equivalence of acceleration field and gravitational field. Advance of
the perihelion (point of closest approach to sun, opposite the aphelion
or point of greatest distance) of Mercury.
- Some other big ideas in Physical Science that will not be much covered
here:
- Thermodynamics and Statistical Mechanics - irreversibility - the
amount of disorder or entropy always increase. For example, putting
a container of hot water and a container of cold water in good
contact with each other always results in warm water. The warm water
never separates back into hot and cold, although energy
considerations alone would not forbid this. The impact is that
energy can never be recycled the way matter ("stuff") can.
Thermodynamics is the field that first established this; Statistical
Mechanics is the field that explains why. The why is that there is a
very much larger number of ways for the molecules in the water to be
arranged with the water warm than there are for it to be separated
into hot and cold.
- Plate Techtonics, also known as "Continental Drift" -
the continents, heated from below, move around the earth's surface
like a skin on boiling milk or pudding.
- Final exam
- New questions for list - fields coming together, example of light, carry
over from old
- Describe one case in which two expanding fields of science met.
What happened within each field. What happened outside of these
fields?
- (#10 from Midterm list) Compare the contributions of Aristotle and
Archimedes to modern science. How did their approaches or methods
differ? How does each compare with modern approaches to science?
- What should be on info sheet? My goal here.
- Start review.
- Readings: Atomic theory of Matter. "Second Scientific
Revolution"
- Steps:
- Invention of classical chemistry and Antoine Lavoisier (1743 -
1794, pronounced lah vwahz YAY). Up until this time, chemistry was
almost entirely a black art. It was important economically, but
chemistry was mainly done through recipes.
- The idea of an element - cannot be broken down, other
substances are made up of it, but it is not made up of anything
else. Still the Aristotelian elements - air, earth, fire and
water.
- Stephen Hale, 1727 - could heat many substances and drive off
large quantities of "air" (we would call it gas today)
- air was not a single substance.
- William Cullen and Joseph Black - evaporation cooled the
liquid left behind. Supposed to be liquid dissolving in air, but
this happened even in a vacuum, with no air in which to
dissolve.
- Turgot - quality of air to fill the container. Happened
because fire attached to the air. Water could take on solid,
liquid and gaseous states, even in contact with each other.
- Black heated chalky substances and drove off air, by weighing
materials left behind, found that this air had weight. Air was
fixed in the solid before, released by heat, also by acid. This
air, however, stopped flames (CO2).
- Joseph Priestly collected many different airs, heated calx.
Calx - compounds of a metal with oxygen, can heat the metal and
drive off some of the oxygen or heat it with carbon and be left
with the pure metal and a gas ("air"). Calx weighed
more than metal. Phlogiston theory of combustion, released
during combustion, can be returned by heating with charcoal to
form pure metal again. But did phlogiston have a negative
weight?
- Lavoisier collected air from heated calx, did not support
combustion, so must be "fixed air." But calcination
will not take palce in an atmosphere of fixed air. Heated in
closed containers, weighed same after as before, so fire or heat
did not carry off any matter. Could heat calx of mercury without
charcoal and it would turn into mercury metal and air, supported
combustion. Could reduce volume by adding nitrous oxide
("nitrous air"), acted like common air, but he could
have added more air and gotten a greater reduction. Priestly
added more and got a further reduction. Also extremely good air
(e.g. mouse lived a very long time).
- Lavoisier hypothesized that common air was actually a mixture,
called it oxygen ("acid former").
- "Inflammable air" (hydrogen) - Cavendish sparked
this with common air, formed a dew later found to be water (so
water was not an element).
- Oxygen theory of combustion, new set of names for chemicals
based on this. Changed "air: to "gas" and used
"air" for former common air.
(Idea of an atom. Very small, gas is mostly empty space. At same
temeprature and pressure, all gases have the same number of atoms in
each volume, different densities are due to the different weights of
the atoms.In a solid, atoms are fixed rigidly to each other, in a
liquid the atoms stay close together but can slide around. Atoms
have different weights and shapes, but mostly just blobs. 90
naturally occurring types, these are the elements.)
- Atomic model, for gases. John Dalton (1766 - 1844)
- (From Gerald Holton, Introduction to Concepts and Theories
in Physical Science, 1973) Dalton apparently became
convinced of the existence of atoms through a misreading of
Newton's Principia. Dalton was interested in why gases did not
stratify by density in the atmosphere, and thought that Newton
wrote that atoms in a gas attracted each other gravitationally,
and that this is what kept them up.)
- General "Law of Definite Proportions." Chemical
reactions always involved fixed proportions, supported the diea
of atoms.
- Noticed that running a current through water gave off twice as
much hydrogen as oxygen, assumed (correctly) that this was
because of the number of atoms of each; water had two atoms of
hydrogen for every atom of oxygen. But oxygen weighed more, so
oxygen atoms weighed more than hydrogen atoms. In this way,
worked out the atomic compositions of many chemicals, and the
relative weights of atoms., without ever detecting an atom
directly.
- Ludwig Boltzmann, end of 19th century. Physicist had never
accepted idea of atoms, did not believe in them. Boltzmann, a
physicist, was one of the first. Worked out Newtonian mechanics for
a gas of atoms and molecules - Statistical Mechanics, together with
J. Willard Gibbs. Found that it gave the same results as
Thermodynamics, but also explained how those results came about. But
physicists sharply rejected these ideas, and this may have
contributed to Boltzmann's suicide in 1906. But now Boltzmann is
honored as a pioneer, ideas are very important, although
significantly modified by Quantum Mechanics.
- Global warming from the early elements C, H, O, N.
- Fossil fuels are C and H, air is O and N. C and 2 O's combine to
give CO2, carbon dioxide, H and O combine to give H2O,
water. Everything else, such as N and O forming NO2, is a
poison or severely degrades the environment. But CO2 is a
greenhouse gas, traps heat in atmosphere, warms up the earth.
Sunlight and heat radiation (infrared) are both electromagnetic
radiation, but light can penetrate the atmosphere, while infrared
(given off by warm objects) cannot, and gets reflected back to
earth.
- Facts:
- CO2 will do this.
- The earth is warming.
- Strong scientific consensus that man-made CO2 is
causing the warming. There is a serious question about how much
heating is going on.
- If second and third world industrialize to our level (and it is
their announced intention to do this, and our announced intention to
help them do it), then levels of CO2 will rise to six
times current levels.
- We know enough about the physical world to know that significant
warming will occur.
- We do not know enough about biological world to predict what the
effects will be, but there will be many.
- Also, we do not know enough about our society, including our
economy, to predict what those effects will be.
- Video - Newton's Laws; The
Apple and the Moon.
- Lab X on circular motion.
- Formula. a = v2/r. F = ma so F = mv2/r for
circular motion. Cornering. angular velocity w
= v/r, so a = w2r, F = mw2r
- Perihelion of Mercury
- No springs, no standard stretches, just swing the weights. Do this
outside or in the corridor. Make sure the knots are tight , the strings
tight around the bottle necks, and hold tightly, your fellow students
will have to make the observations.